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Green Chemistry: The Nexus Blog

116 Posts authored by: ACSGCI

The American Chemical Society’s Green Chemistry Institute (ACS GCI) Chemical Manufacturer’s Roundtable has received a $500,000 Advanced Manufacturing Technology Consortia planning grant from NIST. The grant will help the Roundtable develop greener and more efficient processes that can be used in chemical manufacturing.

 

In particular, the project team seeks to develop a Technology Road Map to propel the design of more energy-efficient alternatives to distillation, the most common separation process across the chemical manufacturing industry. Amit Sehgal Ph.D., of Solvay USA, Inc., the Roundtable Co-Chair stated, starting with molecular chemistry, they “envision a broader range of molecular properties or interactions (inter-molecular and molecular-material) to drive separations with an end goal of providing a logical decision tree based on intrinsic properties for an efficient, sustainable and least energy-intensive separation process.” Led by the ACS GCI Industrial Roundtables, this project is collaboration among the American Institute of Chemical Engineers Separations Division, the Computational Molecular Simulation & Engineering Forum, the Industrial Fluid Simulation Collective, the Pine Chemicals Association and several ACS GCI Industrial Roundtable member companies.

 

The ACS GCI Chemical Manufacturer’s Roundtable will attend the 19th Annual Green Chemistry and Engineering Conference July 14-16, 2015, as part of its yearly collaborations on advancing green chemistry. The industrial roundtable brings global industry leaders together to catalyze the beneficial implementation of green chemistry and engineering.

 

 

 

“The Nexus Blog” is a sister publication of “The Nexus” newsletter. To sign up for the newsletter, please email gci@acs.org, or if you have an ACS ID, login to your email preferences and select “The Nexus” to subscribe.

 

To read other posts, go to Green Chemistry: The Nexus Blog home.

Contributed by Jeffrey Whitford, Director of Global Citizenship at Sigma-Aldrich

 

In a world of constrained resources are you thinking about water use – specifically in your research?  If you answered yes, maybe you live in California, where Governor Jerry Brown has issued an executive order to reduce water usage by 25%, or maybe you live in another part of the world where access to water is a current or consistent challenge.

 

One of challenges that water conservation efforts face is a lack of incentive to conserve water.  There have been many articles written and even a series on NPR’s Marketplace about the low price we pay for water in many parts of the world, consistently undervaluing the resource.  And while the fervor of the alarm rises, our behavior is still not changing.  Without clear financial incentives to make conservation a priority, we have to take individual ownership beyond turning the faucet off while you brush your teeth, taking a three minute shower, or living with a brown lawn.

 

As a business, one of our most important responsibilities is to provide our customers with the products they need to complete their research, which requires that we maintain our license to operate.  You may ask what a license to operate has to do with water. As a manufacturer, water is a key part of what we do – whether it is an ingredient in a product or part of a manufacturing process.

 

As a business, Sigma-Aldrich utilized approximately 1.9 million cubic meters of water in 2014.  While this sounds like a lot, and it is, where and how that water is used is just as important and is part of being a good steward of resource usage.  Sigma-Aldrich also focuses on consistently monitoring and understanding where water is being used and the potential strains that exist on water infrastructure in the communities where we operate.

 

In 2013, Sigma-Aldrich reported a slight increase of water usage in high risk areas, from 11% to 12% of our total usage.  A majority of our water usage is in low risk areas, approximately 74%, while the remaining 14% is in medium risk areas.  A majority of our water usage is in St. Louis, Missouri, at the Production Campus responsible for the manufacture of a significant portion of Sigma and SAFC branded products.

 

Even with low financial incentives and a seemingly endless supply of water, since 2009 Sigma-Aldrich has saved more than two million cubic meters of water through efficiency efforts and by implementing a re-engineering program to rethink how we manufacture products to decrease the environmental impact of manufacturing in the reagents and chemical industry and ensuring that we maintain our license to operate.  We’ve taken this effort to the next level with an industry leading green chemistry quantification system called DOZN™, which captures the environmental improvements we make to products based on the 12 Principles of Green Chemistry.  You can learn more about this system on our website by visiting www.sigmaaldrich.com/dozn.

 

We all have a responsibility to think about how we use resources, but more importantly to think differently and to apply the 12 Principles of Green Chemistry in new and unique ways that challenge the status quo around resource utilization in research.  It’s the curious nature of research that can change the future.  The power of science can raise the bar.

 

 

 

“The Nexus Blog” is a sister publication of “The Nexus” newsletter. To sign up for the newsletter, please email gci@acs.org, or if you have an ACS ID, login to your email preferences and select “The Nexus” to subscribe.

 

To read other posts, go to Green Chemistry: The Nexus Blog home.

ACSGCI

Message from the Director

Posted by ACSGCI May 27, 2015

Contributed by David Constable, Director, ACS Green Chemistry Institute®


So much has happened since my last Nexus article that I’m not sure I can do justice to everything.  Once again, this is a great problem to have!  In mid-April I was fortunate to be invited to the Autonomous University of Nuevo Leon in Monterrey, Mexico for their 3rd International Green Chemistry and Engineering Conference. I was not sure what to expect beyond the enduring hospitality of the people of Mexico, and I was certainly not disappointed in any way. The University boasts a student population of 167,000 and a Chemistry and Chemical Engineering student population of 4,000. I don’t know too many Universities that can claim that kind of impact. The Conference was a great opportunity for students and faculty to present their work, along with a number of industry people I can only hope that the level of commitment, enthusiasm, interest, respect and ambition could be exported to the U.S.; these students were great to be around and I was very impressed.  Mexico has many opportunities to implement greener chemistry and engineering solutions and I am confident that the students are being prepared to accomplish this.

 

The following week was the annual Roundtable meeting of the Green Chemistry and Commerce Council, in Portland, OR. The GC3 is celebrating their 10th anniversary this year, just like the ACS GCI Pharmaceutical Roundtable. Portland is a great place to have a meeting and I am looking forward to holding the 20th Annual GC&E Conference in Portland next year. The GC3 Roundtable is a different experience than the GC&E Conference since it is limited to about 150 people, and it is a business-to-business oriented meeting. In addition to a variety of speakers and workshops, the GC3 discussed the results of work they had been carrying out on mainstreaming green chemistry and better understanding the business case for green chemistry. This meeting, like many others, impresses upon me the enduring difficulty of implementing green chemistry and engineering solutions across the value chains of the goods and services we all know and use. A disconnect remains between the entrenched interests of the chemical industry and the desires of consumers for the types of chemicals in the products they purchase. I think it is fair to say that there is a considerable amount of innovation that will be required to bridge the current divide.

 

The ACS GCI Chemical Manufacturers’ Roundtable received great news in early May that their proposal to the National Institute of Science and Technology Advanced Manufacturing Technologies Program was funded. This is a 2-year, $500,000.00 planning grant to develop a roadmap for the development of alternative separations technologies to what is currently the most commonly used separations technology in the chemical processing industries – distillation. Distillation alone accounts for 25% of the energy use in chemical manufacturing, so implementing less energy intensive separations technologies has a strong economic and environmental incentive. The Project Team is looking to parlay the technology roadmap into a sustainable consortium committed to the development and implementation of new technologies.  No small feat in just two years! This project begins June 1 and we are working already to bring the right people together to make this happen. Please do let us know if you have any questions or would like to be a part of this effort.

 

Last but not least, we are busily preparing for the 19th Annual Green Chemistry and Engineering Conference to be held in

N. Bethesda, MD July 14th through the 16th. The Conference Organizers have been working since last July on this conference and it is shaping up to be another great conference. There are so many activities the entire week, beginning with an NSF sponsored workshop for students and the 20th Annual Presidential Green Chemistry Awards Ceremony on Monday, and ending with an ACS GCI Pharmaceutical Roundtable meeting on Friday. There is so much going on that you simply have to come to be a part of it.  And if you are there, be sure to thank the Technical Program Chairs, the ACS GCI Staff, the sponsors and exhibitors, the ACS GCI Industrial Roundtable members and many others for putting on the best green chemistry event of the year.  I hope to see you there!

 

As always, please do let me know what you think.

 

 

 

“The Nexus Blog” is a sister publication of “The Nexus” newsletter. To sign up for the newsletter, please email gci@acs.org, or if you have an ACS ID, login to your email preferences and select “The Nexus” to subscribe.

 

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Do you want to make an impact on issues like climate change, reliance on fossil fuels,  environmental contamination, unsafe chemicals in consumer products, and conflict minerals use?

 

VOTE for the next wave of innovation that will provide real solutions to these problems through your support of the ACS Green Chemistry Institute’s® 2015 Green Chemistry & Engineering Business Plan Competition.

 

These pressing global issues are impacted by chemistry, and green chemistry holds the key for addressing these critical environmental, health, and cost concerns. Everyone has a stake in this decision, and YOU can ensure greener products will be one step closer to the market place. This is the only competition of its kind exclusively dedicated to green chemistry and engineering and provides the chance for sustainability-oriented entrepreneurs to move their green innovations to a commercial reality.

 

This is your chance to help accelerate solutions to some of the world’s biggest challenges like:

  • Dependence on endangered elements in chemical processes
  • Displacing petrochemicals by transforming renewable or waste feedstocks into valuable chemicals
  • Reducing hazardous chemical inputs in products and processes
  • Minimizing energy use and emissions

 

Click here to cast your vote for the "Change the World with Green Chemistry" campaign!

 

Sign up by July 10, 2015 to help choose a winner. You will be contacted after you select your level with the voting ballot. 100% of proceeds go to the Grand Prize Winner of the competition.

 

Meet the 5 semi-finalist teams--follow the links to hear their first round pitches!


IBEX

Dedicated to the development of bionomic products in the areas of Agriculture, Environmental Remediation, Bio-Industry, and Human Health. (Translation coming soon).

 

SustAnalyz

Data-driven software that speed up the development of sustainable chemicals by increasing efficiency of chemical R&D processes. (Live video coming soon).

 

Verdant

Genesis Reclaimers advance chemical recycling technology. Automation makes recycling practical in any lab.

 

Purdue

Creating a power source from recycled packing peanuts.


Effuelent

Created the Waste Grease Extraction process, the technology that utilizes troublesome substances straight from the waste water facilities, reducing damage to their equipment and the landfill.

 

 

The final round of the competition will take place on July 15, 2015 at the 19th Annual Green Chemistry & Engineering Conference. Visit the conference website to learn more and register for this exciting event!

 

 

 

“The Nexus Blog” is a sister publication of “The Nexus” newsletter. To sign up for the newsletter, please email gci@acs.org, or if you have an ACS ID, login to your email preferences and select “The Nexus” to subscribe.

 

To read other posts, go to Green Chemistry: The Nexus Blog home.

ACSGCI

Surfing into a Green Future

Posted by ACSGCI May 22, 2015

Written by Kim Mcdonald, Biological Sciences, UC San Diego News Center

 

The world’s first algae-based, sustainable surfboard was produced by UC San Diego biology and chemistry students.

UC San Diego’s efforts to produce innovative and sustainable solutions to the world’s environmental problems have resulted in a partnership with the region’s surfing industry to create the world’s first algae-based, sustainable surfboard.

algae-surfboards-mayor-san-diego.jpgThe surfboard was publicly unveiled and presented Tuesday evening, a day before Earth Day, to San Diego Mayor Kevin Faulconer at San Diego Symphony Hall, where he hosted the premiere of the National Geographic “World’s Smart Cities: San Diego” documentary. The program, which features innovations from UC San Diego, is scheduled to air Saturday, April 25 and May 2 on the National Geographic Channel.

 

“Our hope is that Mayor Faulconer will put this surfboard in his office so everyone can see how San Diego is a hub not only for innovation, but also for collaboration at many different levels,” said Stephen Mayfield, a professor of biology and algae geneticist at UC San Diego who headed the effort to produce the surfboard. “An algae-based surfboard perfectly fits with the community and our connection with the ocean and surfing.”

 

Mayfield, an avid surfer for the past 45 years, joined Cardiff professional surfer Rob Machado and Marty Gilchrist of Oceanside-based Arctic Foam, the largest surfboard blank manufacturer in North America, to present the board to Mayor Faulconer.

 

The project began several months ago at UC San Diego when undergraduate biology students working in Mayfield’s laboratory to produce biofuels from algae joined a group of undergraduate chemistry students to solve a basic chemistry problem: how to make the precursor of the polyurethane foam core of a surfboard from algae oil. Polyurethane surfboards today are made exclusively from petroleum. “Most people don’t realize that petroleum is algae oil,” explained Mayfield. “It’s just fossilized, 300 million to 400 million years old and buried deep in underground.”

 

Students from the laboratories of Michael Burkart, a professor of chemistry and biochemistry, and Robert “Skip” Pomeroy, a chemistry instructor who helps students recycle waste oil into a biodiesel that powers some UC San Diego buses, first determined how to chemically change the oil obtained from laboratory algae into different kinds of “polyols.” Mixed with a catalyst and silicates in the right proportions, these polyols expand into a foam-like substance that hardens into the polyurethane that forms a surfboard’s core.

 

                                                

 

To obtain additional high-quality algae oil, Mayfield, who directs UC San Diego’s California Center for Algae Biotechnology, or “Cal-CAB,” called on Solazyme, Inc. The California-based biotech, which produces renewable, sustainable oils and ingredients, supplied a gallon of algae oil to make the world’s first algae-based surfboard blank. After some clever chemistry at UC San Diego, Arctic Foam successfully produced and shaped the surfboard core and glassed it with a coat of fiberglass and renewable resin.

 

Although the board’s core is made from algae, it is pure white and indistinguishable from most plain petroleum-based surfboards. That’s because the oil from algae, like soybean or safflower oils, is clear. “In the future, we could make the algae surfboards ‘green’ by adding a little color from the green algae to showcase their sustainability,” said Mayfield. “But right now we wanted to make it as close as we could to the real thing.” The algae surfboard not only represents the kind of collaboration that is the hallmark of UC San Diego, but the fusion of biotechnology, surfing and environmentally conscious thinking that has made the La Jolla campus and its environs such a desirable place to work and live for scientists, innovators and those who cherish the coastal environment.

 

Mayfield said that, like other surfers, he has long been faced with a contradiction: His connection to the pristine ocean environment requires a surfboard made from petroleum. “As surfers, more than any other sport, you are totally connected and immersed in the ocean environment,” he explained. “And yet your connection to that environment is through a piece of plastic made from fossil fuels.

Now surfers can have a way to surf a board that, at least at its core, comes from a sustainable, renewable source." “In the future, we’re thinking about 100 percent of the surfboard being made that way—the fiberglass will come from renewable resources, the resin on the outside will come from a renewable resource,” Mayfield said. “This shows that we can still enjoy the ocean, but do so in an environmentally sustainable way,” he added.

 

This story is available at: http://ucsdnews.ucsd.edu/feature/surfing_into_a_greener_futur

From the UC San Diego News Center

 

 

“The Nexus Blog” is a sister publication of “The Nexus” newsletter. To sign up for the newsletter, please email gci@acs.org, or if you have an ACS ID, login to your email preferences and select “The Nexus” to subscribe.

 

To read other posts, go to Green Chemistry: The Nexus Blog home.

Next Phase Kicked-off with Special Issue of Aldrichimica Acta

 

Company's top-ranked* chemical review journal to feature commentary from thought leaders in green chemistry


Sigma-Aldrich Corporation (Nasdaq: SIAL), a leading life science and high technology company, today launched the next phase of its global green chemistry initiative. The program, which aims to reduce the chemical-related impact on human health and the environment, kicks off with the first-ever "green" issue of the Company's chemical review journal Aldrichimica Acta. Professor Bruce H. Lipshutz, Guest Editor, commented, "This thematic issue of the Acta offers the chemistry community a unique opportunity to gauge the progress, and glimpse into the future direction, of a broad research effort aimed at increasing awareness of the importance of sustainability in the practice of chemistry, and at inventing ways to mitigate the adverse impact of experimental chemistry on the environment." This special issue contains the latest thinking from 15 of the world's foremost experts on green chemistry. The launch of this issue is accompanied by an exciting update of the Company's green website, SigmaAldrich.com/green, which acts as a core information hub, providing a rich source of shareable content on all aspects of green chemistry.


"In curating this latest issue of Aldrichimica Acta, we have combined commentary from the 'fathers' of green chemistry, as well as published articles and cutting-edge research to foster stimulating exchanges, which will inspire further quests in the field," said Dr. Sharbil Firsan, Senior Specialist and Editor of the Aldrichimica Acta. "In our 48-year history, this is one of our most important issues to-date, gathering scientific understanding from the thought leaders who are truly pushing the field forward, with insights that can't be found anywhere else." The continued push toward green chemistry, part of Sigma-Aldrich's more than 10-year commitment to corporate citizenship and sustainability, aligns with a number of the Company's efforts to change the face of science.


In this special issue, readers can find a sampling of the latest news in green chemistry, including trends, academic research and more:


  • The industry's global progress in green chemistry and an academic look at its future direction at companies like Genentech, Amgen and Novartis,
  • Articles written by renowned chemists John C. Warner and Paul T. Anastas, who together developed the Twelve Principles of Green Chemistry in 1991,
  • Green chemistry insights into:  fluorous chemistry; organic synthesis, as well as biocatalysis and biomass conversion, in ionic liquids; and Catalytic C-C Bond Formation and the Hendricksonian Ideal, and
  • The official introduction of  Sigma-Aldrich's "Greener Alternatives Platform," which includes DOZN— an industry first quantitative green chemistry calculator that is based on the 12 principals of green chemistry developed by Anastas and Warner.


"Global Citizenship is in our DNA. For decades, we've operated with the goal of improving the quality of life through science," said Dr. Scott Batcheller, Manager of Chemistry, R&D and Product Management. "Our work in green chemistry is the next iteration of that commitment.  We are enabling our scientists and customers to make discoveries that will move science forward while reducing the impact on the environment."


Sigma-Aldrich has developed a portfolio of products that offer greener alternatives to many chemicals traditionally used in today's research labs.  The green portfolio is the broadest offering currently available on the market and forms an important part of the full product listing of the Company, which is now in excess of 270,000 products. This growing product range of greener chemicals continues to increase the options for the scientific community to reduce the environmental impact of their research. This effort is aligned with the Company's newly designed website, which contains a number of valuable scientific resources, including a greener alternative product icon search that enables chemists to identify and consider greener options via the "Greener Alternatives and Technologies" product lists.


Sigma-Aldrich has previously been recognized for its global citizenship efforts on numerous occasions, this year alone being named to the Dow Jones Sustainability Index and a top 100 Most Sustainable Corporation by the Global 100 Index, as well as receiving prestigious honors for the third consecutive year by The Civic 50 for leadership in social responsibility work in the Materials sector. The Company, which has more than 9,300 employees working in 37 countries, generated $2.79 billion in revenue in 2014, and for many years has invested in Global Citizenship, including green chemistry, as a corporate-wide sustainability initiative. In the period of 2009-2014, Sigma-Aldrich has:


  • Reduced waste by identifying increased beneficial reuse opportunities, resulting in a 16 percent intensity reduction in waste generation,
  • Saved more than two million cubic meters of water by upgrading systems and enhancing manufacturing practices,
  • Achieved a second consecutive year of absolute electricity reduction though energy efficiency investments, and
  • Decreased transportation emissions by shipping more freight by sea, reducing its carbon footprint by almost 2,000 metric tonnes. To learn more about Green Chemistry at Sigma-Aldrich, visit sigmaaldrich.com/green. To receive your complimentary subscription to the Acta, or to access back issues, please visit Aldrich.com/acta.


*Top-ranked: Journal Citation Reports, Science Edition (Thomson Reuters Canada, Ltd.). Sigma-Aldrich is a trademark of Sigma-Aldrich Co. LLC, registered in the US and other countries.


About Sigma-Aldrich: Sigma-Aldrich, a leading Life Science and Technology company focused on enhancing human health and safety, manufactures and distributes 250,000 chemicals, biochemicals and other essential products to more than 1.4 million customers globally in research and applied labs as well as in industrial and commercial markets. With three distinct business units - Research, Applied and SAFC Commercial - Sigma-Aldrich is committed to enabling science to improve the quality of life. The Company operates in 37 countries, has approximately 9,300 employees worldwide and had sales of $2.79 billion in 2014. For more information about Sigma-Aldrich, please visit its website at  www.sigma-aldrich.com.


This story is available at: http://investor.sigmaaldrich.com/releasedetail.cfm?ReleaseID=902708


From Sigma Aldrich

 

 

 

“The Nexus Blog” is a sister publication of “The Nexus” newsletter. To sign up for the newsletter, please email gci@acs.org, or if you have an ACS ID, login to your email preferences and select “The Nexus” to subscribe.

 

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Contributed by Mingxin Liu, graduate student at McGill University

 

Oxidation of aldehyde towards carboxylic acid is a very common reaction in organic chemistry. At the same time, it is also an unavoidable element of the bio-metabolic pathway. In cytoplasm, aldehydes are highly efficiently oxidized into the corresponding carboxylic acid under very mild (37oC) conditions, utilizing oxygen as the oxidant and enzyme as catalyst. Although this process has been running in our body every day, in industry and academia, methods to achieve this transformation still remain very scarce due to the fact that most oxidation conditions cannot halt the oxidation at the carboxylic acid stage. As a result, traditional oxidations of aldehydes usually yield a mixture of different oxidation products. Even till now, oxidation of aldehydes still relies on stoichiometric amounts of expensive and hazardous oxidants, and often require organic solvents which are also eco-unfriendly.

 

Professor Chao-Jun Li and his team at McGill University have been focusing on the study of achieving organic reactions in water for many years. Recently, they addressed the above-mentioned difficulties of achieving aldehyde oxidation by introducing a silver(I)-based homogeneous catalyst. With this catalyst, a wide variety of different aldehydes were successfully transformed into the corresponding carboxylic acids in an extremely high efficiency. The reaction only requires very little or even ppm level of silver catalyst loading, utilizes normal atmospheric oxygen (or oxygen gas) as the sole oxidant, and water as the sole solvent under very mild temperature (50oC). Over 50 examples of different aldehydes, including aliphatic, aromatic, and unsaturated aldehydes with different electronic properties and functionalities, have successfully been oxidized into the corresponding carboxylic acids in excellent to quantitative yields. Chromatography is generally not required in almost all cases. With only 2mg (~360ppm) catalyst loading, the gram scale reaction with benzaldehyde also gave 82% isolated yield, indicating the potential possibility of expanding this methodology to industrial level.

 

Prof. C.-J. Li's Group will continue to explore the potential applications of the silver(I) catalyst.

 

 

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Contributed by Jeffrey Brown, Executive Director of Practice Greenhealth

 

Health care professionals are charged with creating environments that foster quality health care delivery, patient healing and healthy workplaces for staff. For over fifteen years, partner organizations Practice Greenhealth and Health Care Without Harm have worked with thousands of leading hospitals, health care organizations and suppliers to help them take steps to create healthier facilities by making better, more sustainable decisions about the products and services they purchase. The most innovative organizations have adopted an intentional and strategic approach: avoiding products, services, and materials that can have negative impacts on patients, staff, our communities and the environment. In doing this, they’ve aligned their operations with health care’s healing mission. We’ve seen lots of progress since our founding, and 2014 in particular was important, as hospitals across the country took a big step forward in selecting furniture and materials that contain fewer or no toxic chemicals.

 

Creating Healthier Healing Environments

 

Every day, we are surrounded by thousands of products made from chemicals in our homes, workplaces, schools and stores. Hospitals and health care facilities are no exception.

 

Forward-thinking health care facilities are zeroing in on furnishings as another important step toward creating healthier healing environments. In fact, the 2013 Healthier Hospitals Initiative Milestone Report released by Practice Greenhealth showed that health care facility spending is up on products that are leading to a healthier healing environment for patients, staff and visitors who walk through the doors.

 

Practice Greenhealth is working with health care providers to identify chemicals commonly found in furniture that may be hazardous to human health and the environment.

 

Fortunately, manufacturers have found that it is possible to make healthcare products and furnishings for hospitals using chemicals that we believe are less hazardous, or in many cases, have no known human or environmental toxicity.  We believe that these innovations in product manufacture are a win-win for the companies and more importantly, for people who are healing.

 

A Game Changer: For the Health Care Sector and the Supply Chain

 

Last year was a big year in our quest to create healthier healing environments. Early in 2014, the State of California overhauled its 39-year-old flammability rule, allowing furniture manufacturers to meet safety standards without adding hazardous flame-retardant chemicals to foam or fabric used in furniture.

 

Following the California decision, Kaiser Permanente announced that it would no longer purchase any furniture treated with toxic flame retardants. In September, Advocate Health Care, Beaumont Health System, Hackensack University Medical Center, and University Hospitals Health System followed suit, announcing that they too would transition away from toxic chemicals commonly found in furniture. The five health systems spend roughly $80 million a year to furnish hospitals, medical offices and other buildings with chairs, benches, sofas and other furniture.

 

Their decision to purchase flame retardant-free furnishings is a game-changer for the health care sector and the health care supply chain.

 

How to Adopt Safer Purchasing Strategies

 

Practice Greenhealth has already helped hundreds of hospitals across the country take a big step forward in selecting furniture and materials to create a healthier healing environment. As part of the Greening the Supply Chain® Initiative, we created a supplier directory of Practice Greenhealth business members to assist hospitals with what we feel are better purchasing decisions. The directory is a great source of information on what we consider to be environmentally preferable products and services.

 

 

 

“The Nexus Blog” is a sister publication of “The Nexus” newsletter. To sign up for the newsletter, please email gci@acs.org, or if you have an ACS ID, login to your email preferences and select “The Nexus” to subscribe.

 

To read other posts, go to Green Chemistry: The Nexus Blog home.

Contributed by Anne Marteel-Parrish Associate Professor of Chemistry and Chair Frank J. Creegan Chair in Green Chemistry Washington College, Chestertown, MD

 

I am delighted to share my perspective about what I gained as a regular attendee, participant, and now leader at the Annual Green Chemistry and Engineering conference.

 

I attended my first conference in 2001, which was the 5th annual Green Chemistry and Engineering conference. It is hard to believe that this year we will be celebrating the 19th conference of this type. I still remembered this first time, not because it was my first time attending a conference, but because it was the first time I was given the opportunity to contribute an oral presentation as a second-year graduate student. I remember how nervous and mortified I was to answer questions from a group of experts.

 

This conference is my favorite one to attend for the following reasons:

 

1) I am surrounded by people who have the same passion as I do: Green and sustainable chemistry (it always makes me feel like a student at a large university when I attend a huge meeting where there is a rare chance I will bump into somebody I know…)

 

2) The meeting place and number of attendees is not too large so I am not lost in a sea of people going from one room to another.

 

3) The breadth and depth of topics provides the right amount of knowledge for anybody who is either a “newbie” in the field or more of an expert.

 

4) The ideas exchanged go a long way. I always come home with a plethora of new concepts to implement in my Green and Sustainable Chemistry course or in my research projects.

 

5) I am excited to bring my own undergraduate students to this conference and share this memorable moment with them.

 

What I will always remember from this conference is the relationships and friendships forged and renewed during this conference. The connections I made at this conference are sustainable ones! I am always excited to go because this conference helps me learn beyond expectations. I come back rejuvenated, ready to use my critical thinking skills, and apply some of the top-notch principles I learned.

 

Moreover it was my privilege to lead a technical session titled “Green chemistry beyond the bachelor’s degree (and Ph.D.); Green chemistry education" at the 18th Annual Green Chemistry and Engineering Conference last year in Bethesda, MD. I am very grateful for this opportunity. I can’t wait to attend the next conference as a speaker, session leader, or simply to accompany the next leaders of tomorrow: my students. Go green!

 

 

“The Nexus Blog” is a sister publication of “The Nexus” newsletter. To sign up for the newsletter, please email gci@acs.org, or if you have an ACS ID, login to your email preferences and select “The Nexus” to subscribe.

 

To read other posts, go to Green Chemistry: The Nexus Blog home.

ACSGCI

Message from the Director

Posted by ACSGCI Apr 22, 2015

Contributed by David Constable, Director, ACS Green Chemistry Institute®

 

There is always a lot going on in green chemistry and engineering, which is a great thing. I sometimes hear that many people don’t think that is the case and believe that more should be done and at a faster pace. But, from where I sit, there is a lot going on and green chemistry is being discussed and implemented more and more with each passing day.

 

Just take the ACS National Meeting as one example. For anyone who hasn’t been to an ACS national meeting, you should try and go at least once to experience the breadth and depth of the meeting. On any given day, several technical divisions are sponsoring sessions on some aspect of chemistry that falls under the umbrella of sustainable or green chemistry and engineering principles. These sessions aren’t always labeled as sustainable or green chemistry or engineering, but a quick look at what is being presented should demonstrate that there’s a lot to offer in these areas. To be clear, what is being presented isn’t always about toxics elimination either (actually, it usually isn’t) and the presenters may not actually consider what they are doing to be sustainable or green chemistry and engineering, but that doesn’t mean it isn’t. The bottom line for me is that I’m greatly encouraged to see all the programing that is available at the ACS National meetings and I hope that it continues.

 

Another major event for the ACS GCI that is not terribly apparent to anyone outside of the Institute, is our twice a year Board meeting. For those who are unfamiliar with the ACS and how it operates, there are many governance structures to oversee the work of the ACS, and one of those is the ACS GCI Board. For a complete list of who is on the ACS GCI Board click here. The Board is responsible for overseeing the work of the ACS GCI, sets its strategic direction, and discusses what it thinks we should be doing. We had a good meeting in early April and some excellent discussions on several projects, partnerships and alliances with other green chemistry organizations, and how best to proceed in a world of ever-increasing green chemistry and engineering organizations.

 

The same week of the Board meeting the Organizing Committee for the Green Chemistry and Engineering Conference met to finalize the technical program for the 2015 conference scheduled for July. The Conference is shaping up to be another great year with solid technical programming thanks to the hard work of the organizing committee and their session chairs. Many don’t realize that the Organizing committee has been at work since last summer and very engaged in making the conference a reality. For those of you that had not heard elsewhere, we were greatly saddened by Dr. Richard Wool’s untimely passing in late March. Richard had been such a strong force in green chemistry and engineering for a long time and was very active and committed to making the conference a great event this year. We will miss him greatly, but we were pleased to welcome to the organizing committee a former student of Richard’s, Dr. Joseph F. Stanzione, a professor at Rowan University, to take up where Richard left off. Finally,

 

I’d like to acknowledge the ACS GCI Pharmaceutical Roundtable's successful meeting in Basel, Switzerland, the week of 13 April. For those of you that don’t know, the Pharma RT is celebrating its tenth year anniversary  and in addition to their normal meeting, they had a great one-day symposium on green chemistry to help them celebrate. The ACS GCI Pharma RT continues to make a number of significant contributions to green chemistry and engineering, and I look forward to their continuing success over the next ten years.

 

So, I’ll end as I began; there’s a lot going on in green chemistry and engineering, and while it may not be apparent to everyone, it’s undoubtedly a good thing. As always, please do let me know what you think.

 

 

 

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Contributed by Douglas Fox, Department of Chemistry, American University, Washington, DC

 

Our research group helps to improve the sustainability of buildings and cities by focusing on the development of affordable and effective flame retardants that are synthesized from natural products. These flame retardants are blended with plastics or formulated into a coating for use in flexible foams and wood based products. Some have been used in bio-derived plastics to reduce their flammability without the typical degradation of desirable polymer properties, thereby increasing the number of commercial applications for these types of plastics.

 

Plastics, polymers, and polymer composites have become ubiquitous over the past 60 years. In 2013, nearly 300 million metric tons of plastic were produced, making it one of the most used materials worldwide on a volume basis. Their increased use can be traced to their inherent properties: strong, lightweight, flexible, moldable, and inexpensive.  In addition, it is relatively easy to incorporate additives to tune their properties. These composites can be tailored to achieve desired properties on opposite ends of the spectrum by simply mixing molten polymer and filler using an extruder.

 

For example, addition of glass, carbon, or natural fibers increase strength and stiffness. Addition of a plasticizer decreases tensile strength and softens the composite. Addition of clay can reduce diffusion of gases or solvents, whereas incorporation of water soluble salts during extrusion can increase voids in the processed plastic. Or, the addition of benzophenones aids used to protect the polymer from photodegradation, while the addition of titanium dioxide can be used as a photoinitiator to accelerate UV degradation of the polymer.  But plastics also come with a range of disadvantages, presenting major challenges. They are inherently flammable, increasing the risk and costs of fire.  Most of the monomers, or building blocks of the polymer, and many of the fillers used to tailor the properties, are toxic, bioaccumulative, or persistent chemicals, posing many health concerns, both real and perceived. And, they are generally durable. Combined with their low densities (lightweight), this generates a major waste management issue. Recycling has alleviated some of the waste burden, but plastics still represent over 20% of the waste in landfills, and over 5 million tons of plastic finds its way in oceans every year.

 

Nexus picture.jpgOne of the more difficult disadvantages to address is the high flammability of plastics. In the United States, fires account for over 3,000 deaths, 16,000 injuries, and $11 billion in property loss every year. This represents a major decline over the past few decades. Part of this reduction can be attributed to the use of flame retardants in residential upholstered furniture, which reduce the toxicity of combustion products and allow for longer egress times during fires. Fires can be started by either open flame sources, such as candles or matches, or by smoldering sources, such as cigarettes or incense. There are many methods that can be used to address these problems, such as use of smolder resistant fabrics, back-coating fabrics, or the addition of flame retardants. Recently, there has been increasing concern over the migration, persistence, potential toxicity, and perceived lack of efficacy of flame retardants typically used in furniture and flexible foam. This has led to public debate, regulation changes, and increased pressure to find alternatives. The alternatives include both approaches to reducing fire risks as well as development of safer, less transient, more efficient flame retardants.

 

The largest concern of the increased use of plastics is probably the problems associated with their disposal. There is an increased public awareness of the growing risks associated with waste, pollution and the need for more sustainable products and practices.  The most widely used plastics are synthesized from petroleum distillates, generating a resource and energy sustainability issue.  These plastics do not biodegrade, but will photodegrade into smaller fragments. This leads to the leaching of the starting materials and fillers used in the production of the composites, many of which are toxic to plants and animals alike. In addition, the small photodegraded plastic fragments are consumed by animals in the wild, which are also toxic or disruptive to their life cycle. This persistence, bio-accumulation, and toxicity of leached chemicals leads to a loss in biodiversity, which can affect the sustainability of entire ecosystems. Resolving this issue is quite complex due to technical, societal, economic, and logistical issues. Attempts have been made to produce biodegradable plastics and/or plastics from bio-derived sources, such as starch based plastics, soybean based epoxies, and corn based poly(lactic acid). Unfortunately, these plastics possess properties that are inferior to their petroleum based counterparts and often cost much more to produce. There are a large number of scientists and engineers working on addressing these issues, and much progress has been made. With the addition of select additives and cheaper production practices, these bio-based and biodegradable plastics have slowly been making their way into the marketplace. Much of their use today has been limited to plastic utensils and packaging applications, but their blends with more traditional petroleum based plastics have also been explored for use in textiles and electrical equipment.

 

We are addressing these issues by developing more sustainable polymer nanocomposites with improved flame resistance and better compatibility between the filler and polymer. These composites would be used primarily in the home or businesses, helping to develop more sustainable cities. We have two primary goals in our work:

 

  1. The use of fillers and crosslinkers to improve the water resistance and mechanical properties of bio-derived polymers.
  2. The modification of natural materials to improve both interfacial adhesion and flame retardant properties of the polymer.

 

In many of our systems, we have addressed issues in both of these areas simultaneously.

 

Our primary focus is currently on the development of flame retardants using natural materials. We began with using cellulose as a replacement for one of the components in an intumescing flame retardant. An intumescing flame retardant produces a foaming char barrier through the use of a dehydration source (typically an acid), a carbon source (such as pentaerythritol), and a gas forming source (typically a polyamine). The use of cellulose fibers is more sustainable than traditional carbon sources used in intumescing flame retardants and can improve mechanical strength and stiffness if there is good interfacial adhesion with the polymer. To increase the amount and mechanical durability of the char during combustion, we utilized silicon containing materials. The modification of cellulose using a reactive POSS molecule (POSS is a hybrid between silica (SiO2) and silicone (R2SiO) that can be attached directly to polymer chains) was effective for flame retarding poly(lactic acid) while preventing the hydrolytic decomposition of the polymer during processing and preventing the loss in mechanical properties that typically accompanies this hydrolytic decomposition. The addition of organically modified clay was only partially effective due to the inability to fully separate the clay layers during processing.

 

Intumescing flame retardants suffer from the need for multiple components with variable surface energies and morphologies as well as moisture sensitivity, leading to the leaching of flame retardant during weathering and poor interfacial adhesion with some polymers. We are examining methods to utilize cellulose fibers for an all-fiber intumescent.  We phosphorylated the POSS modified cellulose to add the acid source needed to promote char. The level of phosphorylation was insufficient to replace typical acids, but the improvements observed were encouraging for future studies.  We recognized that starting with cellulose nanocrystals (CNCs), which have greater reinforcing potential, may be more advantageous than using cellulose fibers. CNCs that are produced from oxyanionic acids (like sulfuric acid) participate in side esterification reactions with the oxyanion. Use of sulfuric or phosphoric acid would produce CNCs that contain acidic sulfur or phosphorus groups, both of which are typically good flame retardants.  We have experimentally determined that sulfuric acid produced CNCs have a lower thermal stability but better flammability characteristics than unmodified cellulose fibrils. We are currently developing modification methods to simultaneously increase the thermal stability of the CNCs and modify the surface energy to improve interfacial adhesion with hydrophobic polymers.

 

It is difficult to homogenously disperse cellulose fibers or crystals in epoxy thermosets. Most epoxies are quite hydrophobic (poor interfacial adhesion), have high viscosities (mixing difficulties), and take hours to cure (time for suspensions to settle). For these systems, we examined the use of lignosulfonate and tartaric acid as an intumescing flame retardant. Lignosulfonate, which is a by-product of the sulfite pulping process, was very effective as a flame retardant for epoxy composites, but it had a tendency to migrate to the surface during curing.  As a result, the protective layer that forms can crack and peel off the surface when exposed to a radiant heat sources for too long.  We are currently investigating methods to prevent this migration during epoxy curing.

 

The largest fuel source in a home is upholstered furniture. To reduce the fire risks associated with them, the foam had been required to pass both smoldering and open flame fire tests. Manufacturers typically used brominated flame retardants to pass the open flame tests. Due to increasing concern over the persistence, potential toxicity, and perceived ineffectiveness of these flame retardants, industry has renewed interest in flame retardant alternatives. The newest regulations for upholstered furniture does not require an open-flame test, but that does not eliminate the risks associated with these type of fires nor guarantee that they will not be re-established. As a result, there is still an urgent need to develop more environmentally benign flame retardants for upholstered furniture or flexible foam.  In light of these developments, we have been developing flame retardant coatings using natural materials.  We use borate salts (which have been used extensively in wood as anti-fungal agents), phytic acid (which is a phosphate storage molecule in plants), or taurine as the primary flame retardant. To keep the flame retardant from washing away, we use carbohydrates, polydopamine, or food proteins as binding agents. Other natural additives to add char strength, anti-fungal properties, smoldering resistance, or binder crosslinking are currently under investigation.

 

As we design our approaches, we remind ourselves of the need to maintain processability. This includes both process design as well as operating costs.  It is my belief that great studies in sustainable materials and chemistry will not actually improve sustainability unless industry and commercial enterprises are able to technically and economically adopt the process. We welcome additional input from engineers, managers, and industry, especially on optimizing processing techniques, to help us achieve useful, ecologically sustainable products commonly found in homes and cities.

 

 

 

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Contributed by Orion Lekos PhD, WSU Extension Biofuel Specialist

 

Biobased Fuels2.png

Advanced Hardwood Biofuels Northwest (AHB) is a consortium of university and industry partners exploring innovative technology using biological and chemical processes to convert poplar into bio-based fuels and chemicals. During the conversion process from poplar wood chips to renewable transportation fuels, intermediate chemicals are produced, including acetic acid, ethyl acetate, ethanol, and ethylene. These bio-based chemicals can substitute conventional petroleum versions to make products that we use in our everyday lives such as paints, plastics, textiles, solvents, and packaging.  Including a portfolio of high-value chemicals is an important piece of a profitable biorefinery. As the price of oil rapidly changes, biofuels are not always cost effective to manufacture.  A biorefinery that can also produce commodity chemicals is more versatile and able to weather the volatile oil markets. The ability to make chemicals at the large scale of a biorefinery also takes advantage of lower operational costs compared to a chemical plant alone. In general, the chemicals made are also more valuable than the fuel and have higher yields, but fuels sell in larger quantities than chemicals and create a stable income for the refinery.

 

 

 

 

 

From one dry ton of poplar chips we get…


Biobased Fuels.jpg


1270 lbs of Sugars

Poplar chips are converted to sugars through hydrolysis where the cellulose and hemicellulose are broken down into glucose and xylose. The sugar can be sold to ethanol producers or it is fermented in AHB’s process to make acetic acid.

 

 

133 Gallons of Acetic Acid

Acetic acid is in high demand globally for the manufacture of paints, ice melting salts, adhesives, polymers, and solvents. From this point the acetic acid can be sold or further processed on to make...

 

 

115 Gallons of Ethyl Acetate

Ethyl acetate a less toxic solvent than acetone used in nail polish remover, cosmetics, perfumes, and to decaffeinate coffee and tea.  Industrially it is made by an esterification reaction of ethanol with acetic acid.  Depending on market demand, the Ethyl Acetate can be sold or further processed on to make...



135 Gallons of Ethanol

The AHB process is nearly 100 % carbon efficient compared to 67% efficiency for traditional yeast fermentation. The ethanol can be sold or further processed on to make...



288 Gallons of Ethylene

Ethylene gas is normally made from petroleum and is a versatile chemical that is the backbone of the plastics we use every. The ethylene can be converted into jet fuel through polymerization.



80 Gallons of Jet Fuel

Two carbon ethylene gas molecules are combined together catalytically to form hydrocarbon fuel chains. This creates a jet fuel made from poplar trees that can be used in existing airplane engines.

 

 

 

 

 

 

 

 

 

 

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ACSGCI

Remembering Dr. Richard P. Wool

Posted by ACSGCI Apr 21, 2015

1386958373440.jpgDr. Richard P. Wool was a familiar and prominent face in the green chemistry and engineering world, whether he was molding the minds of college students, organizing conferences and events (he was until his recent passing a co-chair of the GC&E Conference this year), or conducting award-winning research. His unexpected passing on March 24th has had a huge impact on the green chemistry and engineering community, where he will be remembered by many.

 

Born in Cork, Ireland, Wool received his Bachelors of Science in Chemistry from the University College Cork, Ireland in 1970. After moving to the U.S., Wool received his Masters in Science and Ph.D. in Materials Science & Engineering from the University of Utah. He taught at many institutions before Wool and his family made a permanent home for the past 20 years at the University of Delaware, where he was Professor of Chemical and Bimolecular Engineering. Wool was the director of the Affordable Composites from Renewable Resources (ACRES) program, where he and his students investigated the use of soybean triglycerides as raw materials in the synthesis of new polymers suitable for liquid molding processes.

Professor-Richard-Wool-copy.png

In 2011, Wool received the ACS Award for Affordable Green Chemistry for developing uses for bio-based materials like chicken feathers and soybeans to create a diversity of products from roofing and housing materials to circuit boards to a synthetic fabric Wool named “eco leather”.

 

In 2013, Richard Wool won the U.S. EPA’s Presidential Green Chemistry Challenge Award for his work in Sustainable Polymers and Composites. The award is the nation’s most prestigious recognition for excellence in green chemistry research that has the potential for positive impacts in commercial application.  He was also elected as a Fellow of the Royal Society of Chemistry and the American Physical Society, Division of High Polymer Physics.  Wool published over 150 papers, wrote two books, and holds four patents.

 

After being present at many Annual Green Chemistry & Engineering Conferences, including a DSCN0070.JPGkeynote address in 2012, Wool was helping to shape the 2015 conference as a co-chair of the organizing committee.  Dr. David Constable, Director of the ACS GCI, stated “he was extremely supportive and active throughout the past year as a Conference Organizing Committee Co-Chair.  We will greatly miss his leadership, good wit, and strong support.”  A former student, Dr. Joseph F. Stanzione, III, Assistant Professor and Graduate Program Coordinator in the Chemical Engineering Department at Rowan University, has joined the GC&E organizing committee in Wool’s honor.  While Wool will be remembered at the GC&E conference for all he has done to advance green chemistry and engineering, his influence extends well beyond and into the future.

 

 

 

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Contributed by Tim Bugg, Department of Chemistry, University of Warwick, Coventry CV4 7AL, UK.

 

Lignin, the aromatic polymer that binds together cellulose and hemicellulose in plant cell walls, is one of the big unsolved problems in the “biorefinery concept”, whereby plant biomass could be used to provide renewable fuels and chemicals for society and the chemicals industry. While great progress has been made in converting cellulose to cellulosic biofuels, and hemi-cellulose to useful fermentation products, lignin is still the problem child that no one quite knows what to do with. It is produced as a by-product of pulp/paper manufacture, and increasingly produced from cellulosic biofuel manufacture, but it is not susceptible to hydrolytic breakdown, and is a rather inert, insoluble material that is usually just burnt to provide heat. But its content of aromatic rings represents a potential source of renewable aromatic chemicals, so surely we could do something better with it than burning it?

 

Since the 1980’s scientists have studied micro-organisms that can break down lignin, the most active organism being white-rot fungus Phanerochaete chrysosporium, which produces an arsenal of extracellular lignin peroxidase and manganese peroxidase enzymes, with other fungi producing copper-dependent laccases. However, the discovery of these enzymes hasn’t yet translated into a commercial process for conversion of lignin into renewable chemicals, partly because fungal enzymes are hard to over-express in large quantities. Hence there has been renewed interest in soil bacteria that can attack lignin. For many years no bacterial lignin-oxidising enzyme had been identified, but in the last few years several bacterial enzymes have emerged. Members of the dye-decolorizing peroxidase (DyP) family of peroxidases have been identified that have activity for oxidation of lignin and lignin model compounds: DypB from Rhodococcus jostii RHA1 was identified by my research group in collaboration with Lindsay Eltis at UBC, and Michelle Chang’s group at UC Berkeley have identified a Dyp2 enzyme from Amycolatopsis sp. 75iv2. Bacterial laccases are also found, particularly in actinobacteria, and John Gerlt’s group at U Illinois have shown that laccase enzymes in Streptomyces A3(2) are involved in lignin breakdown.

 

Can we use these enzymes as biocatalysts to transform lignin into renewable chemicals? It seems so obvious, and yet, unfortunately, it’s not as simple as that, because the same enzymes that depolymerise lignin also polymerise the radical intermediates formed, generating higher molecular weight material. So you get competing depolymerisation and repolymerisation, in other words, one step forward and two steps back. Somehow Nature appears to solve this problem, we don’t know exactly how at present.

 

So could we use microbial fermentation to transform lignin into chemicals? This approach is starting to yield some interesting results. Although our knowledge of the metabolic pathways for lignin breakdown is very incomplete, there are indications that vanillic acid is one key intermediate in lignin breakdown. In Rhodococcus jostii RHA1, the group of Lindsay Eltis identified the genes responsible for oxidation of vanillin to vanillic acid, and then demethylation to protocatechuic acid, and generated gene deletion strains lacking these genes. When we tested the gene deletion strain for vanillin dehydrogenase, we found that when we grew this strain on minimal media containing chopped wheat straw, we could detect vanillin (for which there is a market in the food/flavour industry) as a metabolite. Under optimised conditions we obtained a yield of 96 mg/litre vanillin, not quite an industrially useful yield, but a big step forward, showing that synthetic biology could in principle be used to generate aromatic chemicals from lignin breakdown. We now hope to use this kind of approach to generate other aromatic compounds for industrial applications, and my group is collaborating with Biome Bioplastics to try to generate products from lignin that could be used to make new bio-based plastics to replace oil-based plastics, as described on:

 

 

There is still a long way to go: we still don’t fully understand the degradation pathways, we know little about how lignin degradation is regulated, and how lignin fragments are taken up into bacterial cells. But that also makes it an interesting area for study, and despite a strong dose of scepticism that I’ve encountered sometimes, I personally believe that it will be possible to convert lignin into renewable chemicals, maybe using biocatalysis, or chemocatalysis, or some combination of the two approaches. Not only do I think it’s possible, but I think we have to find a way to do this, to provide an alternative to petrochemicals for tomorrow’s Society.

 

References

 

Bugg TDH, Ahmad M, Hardiman EM, Singh R (2011). The emerging role for bacteria in lignin degradation and bio-product formation. Curr. Opin. Biotech., 22, 394-400.

 

Ahmad M, Roberts JN, Hardiman EM, Singh R, Eltis LD, Bugg TDH (2011). Identification of DypB from Rhodococcus jostii RHA1 as a lignin peroxidase. Biochemistry, 50, 5096-5107.

 

Brown ME, Barros T, Chang MCY (2012). Identification and characterization of a multifunctional dye peroxidase from a lignin-reactive bacterium. ACS. Chem. Biol., 7, 2074-2081.

 

Majumdar S, Lukk T, Solbiati JO, Bauer S, Nair SK, Cronan JE, Gerlt JA (2014). Roles of small laccases from Streptomyces in lignin degradation. Biochemistry, 53, 4047-4058.

 

Sainsbury PD, Hardiman EM, Ahmad M, Otani, H, Seghezzi N, Eltis LD, Bugg TDH (2013). Breaking down lignin to high-value chemicals: the conversion of lignocellulose to vanillin in a gene deletion mutant of Rhodococcus jostii RHA1. ACS Chem. Biol., 8, 2151-2156.

 

For podcast on lignin degradation see: http://www2.warwick.ac.uk/fac/sci/chemistry/research/bugg/bugggroup/research/lig nin/

 

 

 

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Contributd by Zhiqian Wang and Somenath Mitra*, Department of Chemistry and Environmental Science, New Jersey Institute of Technology

 

Battery Pic.jpgThe development of flexible electronics printed on polymer matrices has opened up the possibilities of mobile phones to be folded into the pockets and a variety of electronic products including flexible displays, smart surfaces (Figure 1) and sensors to be made into different bendable shapes, that can be rolled up, twisted or inserted in films. Thanks to flexible organic LEDs and solar cells, it is possible to have rolled up window shades that have solar cells on one side to generate electricity and TV screen on other side for watching the evening news. Flexible batteries rolled up as carpets can be used for energy storage in solar powered green buildings. Other applications of flexible electronics include the “internet of things” such as sensors that go on food packaging and smart tags.  The market for flexible electronics is expected to go from 24 billion in 2014 to over 70 billion by 2024 (source IDTechEx.com). There is an additional requirement for this new electronic revolution to remain “flexible”, and that is the availability of flexible power sources such as batteries. Typical batteries in the market are AA, AAA, D type and Lithium ion batteries. At present, these batteries appear to be the source of inflexibility and researchers are scrambling to develop flexible batteries.

 

The basic structure of flexible battery being developed in Dr. Mitra’s group at New Jersey Institute of Technology is shown below (Figure 2 a). Like all other batteries, a flexible battery is composed of cathode, anode, separator between the electrodes, current collectors, and packaging materials; the only requirement is that each component must be flexible.

                                      Untitled.png

Figure 2. a) Schematic diagram of a flexible battery; b) a flexible electrode; c) flexible batteries powering LEDs.

 

One of the major challenges in the fabrication of such batteries is the flexible electrodes. Traditional electrodes crack and disintegrate on bending. In order to acquire desired performance and flexibility, polymeric binders along with conductive polymers are often added into the electrode to “glue” the electroactive particles together. The requirements can be stringent: the binder should not dissolve in the electrolyte, and the electrodes should have low electrical resistance, high mechanical strength and high reactivity. Thanks to nanotechnology, there can be many options. For example, when traditional conductive materials like graphite cannot meet the specifications, nanomaterials like carbon nanotubes provide an alternative. These nanocarbons are highly conductive, flexible with high mechanical strength, and are chemically inert. Due to their tiny dimensions, these nanotubes can fill the gaps among electroactive particles to form conductive networks more efficiently than graphite, and hence bring down the electrode resistance dramatically. Certain treatment of carbon nanotubes, like purification, may further improve the performance. Furthermore, composition of additives needs to be optimized to maintain a balance between the battery performance and flexibility.

 

Another consideration in the battery fabrication is the separator, which should be electrically insulating but allow ions to pass through. Besides the structure and packaging considerations, a separator needs to store electrolytes and has special requirements in the case of harsh environment such as in an alkaline cell where the electrolyte is a strong base (KOH). Finally, all components need to be packaged into a compact system with good electrical connections. In general the platform for flexible batteries is quite interesting. Various conventional batteries such as zinc-carbon, primary alkaline, rechargeable alkaline as well as lithium-ions are being fabricated. Conventional screen printing, inkjet printing as well as 3-D printing open the doors to inexpensive manufacture of a variety of these batteries to power electronics and harvest energy at home from flexible solar cells.

 

References:

 

  1. Z. Wang, N. Bramnik, S. Roy, G. D. Benedetto, J. L. Zunino III, S. Mitra. Journal of Power Sources, Volume 237, 2013, Pages 210-214.
  2. Z. Wang, Z. Wu, N. Bramnik, S. Mitra. Advanced Materials, Volume 26, 2014, Pages 970-976.
  3. Z. Wang, S. Mitra. Journal of Power Sources, Volume 266, 2014, Pages 296-303.

 

 

 

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