Publication Details (including relevant citation information):
O. Atchade, X. Song, R. Pike, G. Eng,Analytical Sciences, 24, 77-78 (2008)
The title compounds, [(iso-C4H9)2NH2][SnPh3(O2CCH(CH3)S)], crystallized in a monoclinic space group P21ln with the following cell parameters: a = 9.8537(2)Å, b = 16.7775(3) Å, c = 17.5845(3) Å, β = 103.7740(10)° , V =2823.48(9) Å3, Z = 4 and Dx = 1.375 Mg m-3. The structure was refined to a final R value of 0.0222 for 5042 reflections [I > 2σ(I)]. The structure of the complex is ionic consisting of an anionic triphenyltin moiety and a cationic di-iso-butylammonium portion. In addition, a hydrogen bonding network between the cations and anions was observed.
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