Muhammad Javed - Synthesis of Fused and Bridged Bicyclic Diazenium Salts by Intramolecular Cycloaddition

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      Bicyclic diazenium salts are synthesized by a Lewis acid mediated   intramolecular cycloaddition


      Bicyclic diazenium salts were efficiently prepared by a Lewis   acid mediated intramolecular cycloaddition. Terminal olefins   provided mixtures of fused and bridged bicyclic diazenium salts.   The α-chloroazo cycloaddition precursors were conveniently   prepared from the corresponding phenyl hydrazones by treatment   with chlorodimethylsulfonium chloride.

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