Masato Ito - Highly Enantioselective Hydrogenative Desymmetrization of Bicyclic Imides Leading to Multiply Functionalized Chiral Cyclic Compounds

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      Highly enantioselective hydrogenative desymmetrization of   bicyclic imides has been developed with chiral Cp*Ru(PN)   catalysts. The present hydrogenation directly provides   stereochemically well-defined cyclic compounds with excellent   enantiomeric exessses, which might otherwise require a detour to   reach.

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