Alex Lubnin - Structure of Complexes of Triethylaluminum with Calcium and Magnesium Alkyls According to 1H NMR Data

Document created by Alexander Lubnin on Aug 22, 2014
Version 1Show Document
  • View in full screen mode

  Publication Details (including relevant citation   information):

  Journal of General Chemistry (U.S.S.R.), Vol. 54, No. 6, Part 1, pp.   1170-1174 (1984),


The Ca bistetramethylalanate complex exists as an equil. between the ionic form Ca2+[AlEt4]2- and the trimer I.  The complex from Bu2Mg and Et3Al exist as a mixt. of dimers II and III (R = Et, Bu) with the metal atoms bonded through the alkyl groups.  Et, Bu exchange takes place.

  Address (URL): http://