Veejendra Yadav - DBU-Catalysed Deconjugation of 3,4-Dehydro-2-oxepanones. Deuterium Incorporation, Significance of the Imine Double Bond and Application to the Synthesis of a Key Pharmacophore J

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      Publication Details (including relevant citation   information): DBU-Catalysed Deconjugation of   3,4-Dehydro-2-oxepanones. Deuterium Incorporation, Significance   of the Imine Double Bond and Application to the Synthesis of a   Key Pharmacophore J. Org. Chem. 63, 287-294, 1998. The   Suitability of Anion-Accelerated oxy-Cope Rearrangement as a   Probe to Study pi-Facial Selectivity. An Experimental Study with   (6-Methyl-1-oxa-4-thiaspiro[4.5]dec-6-en-7-yl)(allyl)methanols J.   Chem. Soc. Perkin Trans 1 1423-1428, 2000. Silicon-assisted ring   Opening of donor-acceptor substituted cyclopropanes. An expedient   entry to substituted dihydrofurans Org. Letts 2717-2719, 2001.   Synthesis of gama-methylene oxacycles and alpha- and   beta-alkylidene lactones via silicon-assisted ring opening of   cyclopropyl carbinols Chem. Commun. 514-515, 2002. Formal [3 + 2]   Addition of Acceptor-Substituted Cyclopropylmethylsilanes with   Arylacetylenes Angew Chem. Int. Ed. 43, 2669-2671, 2004. Highly   stereoselective Prins cyclization of silylmethyl substituted   cyclopropylcarbinols to 2,4,6-trisubstituted tetrahydropyrans J.   Am. Chem. Soc. 126, 8652-8653, 2004. Silylmethyl-substituted   aziridine and azetidine as masked 1,3- and 1,4-dipoles for formal   [3+2] and [4+2] cycloaddition reactions J. Am. Chem. Soc. 2005,   127, 16366-16367. Lewis acid-catalyzed formation of indene   derivatives via tandem reactions of arylacetylenes with the   cations generated from silylmethyl-substituted cyclopropyl   carbinols Chem. Commun. 2281-2283, 2007. Total syntheses of   (+)-7-epi-goniofufurone, (+)-goniopypyrone and (+)-goniofufurone   from a common precursor Chem. Commun. 5232-5234, 2007.   2,3-Heteroaromatic ring-fused cyclohexanones via heteroaromatic   ****-Nazarov cylcization of donor-acceptor substituted   cyclopropanes Chem. Commun. 3774-3776, 2008.

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