Vasudeva Sagi - Enantio- and Diastereocontrolled Total Synthesis of (+)-Boronolide

Version 1

      Publication Details (including relevant citation   information):

      J. Org. Chem. 2006, 71,   3935-3941

      Abstract:

      An efficient stereoselective total synthesis of (+)-boronolide   from valeraldehyde is described. The key steps include a   Sharpless asymmetric hydroxylation, a chelation-controlled vinyl   Grignard reaction followed by a Sharpless asymmetric epoxidation,   hydrolytic kinetic resolution, and a ring-closing metathesis.

      Address (URL): http://pubs.acs.org/doi/abs/10.1021/jo0603781?prevSearch=vasudeva%2Bnaidu&search HistoryKey=