Nura Suleiman Gwaram - {2-Morpholino-N-[1-(2-pyridyl)- ethylidene]ethanamine-j3N,N0,N00}- bis(thiocyanato-jN)zinc(II)

Document created by Nura Suleiman Gwaram on Aug 22, 2014
Version 1Show Document
  • View in full screen mode

  Publication Details (including relevant citation   information):

  Acta Cryst. (2011). E67, m131 [ doi:10.1107/S1600536810053778   ]
  {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-   3N,N',N''}bis(thiocyanato- N)zinc(II)
  N. Suleiman Gwaram, N. A. Ikmal Hisham, H. Khaledi and H. Mohd   Ali

  Department of Chemistry, University of Malaya, 50603 Kuala   Lumpur, Malaysia
  Correspondence e-mail:


  The asymmetric unit of the title compound, [Zn(NCS)2-
  (C13H19N3O)], contains two crystallographically independent
  molecules. In each molecule, the ZnII ion is five-coordinated
  by the N,N0,N"-tridentate Schiff base and the N atoms of two
  thiocyanate ligands in a distorted square-pyramidal geometry.
  The two molecules differ mainly in the deviations from the
  ideal geometry, with values of 0.14 and 0.33. In the crystal,
  intermolecular C—H S hydrogen bonds are observed. An
  intramolecular C—H N hydrogen bond occurs in one of the
  independent molecules.

  Received 9 December 2010; accepted 22 December 2010
  Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C)   = 0.003 A°
  R factor = 0.027; wR factor = 0.072; data-to-parameter ratio =   16.3.

  Address (URL): http://