Nura Suleiman Gwaram - {2-Morpholino-N-[1-(2-pyridyl)- ethylidene]ethanamine-j3N,N0,N00}- bis(thiocyanato-jN)zinc(II)

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      Publication Details (including relevant citation   information):

      Acta Cryst. (2011). E67, m131 [ doi:10.1107/S1600536810053778   ]
      {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-   3N,N',N''}bis(thiocyanato- N)zinc(II)
      N. Suleiman Gwaram, N. A. Ikmal Hisham, H. Khaledi and H. Mohd   Ali

      Department of Chemistry, University of Malaya, 50603 Kuala   Lumpur, Malaysia
      Correspondence e-mail:


      The asymmetric unit of the title compound, [Zn(NCS)2-
      (C13H19N3O)], contains two crystallographically independent
      molecules. In each molecule, the ZnII ion is five-coordinated
      by the N,N0,N"-tridentate Schiff base and the N atoms of two
      thiocyanate ligands in a distorted square-pyramidal geometry.
      The two molecules differ mainly in the deviations from the
      ideal geometry, with values of 0.14 and 0.33. In the crystal,
      intermolecular C—H S hydrogen bonds are observed. An
      intramolecular C—H N hydrogen bond occurs in one of the
      independent molecules.

      Received 9 December 2010; accepted 22 December 2010
      Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C)   = 0.003 A°
      R factor = 0.027; wR factor = 0.072; data-to-parameter ratio =   16.3.

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