Nura Suleiman Gwaram - Aqua{2-morpholino-N-[1-(2-pyridyl)- ethylidene]ethanamine-j3N,N0,N00}- bis(thiocyanato-jN)nickel(II)

Version 1

      Publication Details (including relevant citation   information):

      Acta Crystallographica Section E
      Structure Reports
      Online
      ISSN 1600-5368

      Nura Suleiman Gwaram, Nurul Azimah Ikmal Hisham,
      Hamid Khaledi* and Hapipah Mohd Ali
      Department of Chemistry, University of Malaya, 50603 Kuala   Lumpur, Malaysia
      Correspondence e-mail: khaledi@siswa.um.edu.my
      Received 13 December 2010; accepted 15 December 2010

      Abstract:

      In the title compound, [Ni(NCS)2(C13H19N3O)(H2O)], the NiII
      ion is six-coordinated by the N,N0,N00-tridentate Schiff   base,
      the N atoms of two thiocyanate ligands and one water O atom
      in a distorted octahedral geometry. Intramolecular C—H N
      and C—H O hydrogen bonds occur. In the crystal, O—
      H S, O—H O and C—H S hydrogen bonds link
      adjacent molecules into layers parallel to the ac plane.

      Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C)   = 0.003 A°
      ;
      R factor = 0.025; wR factor = 0.058; data-to-parameter ratio =   14.9.

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