Nura Suleiman Gwaram - Aqua{2-morpholino-N-[1-(2-pyridyl)- ethylidene]ethanamine-j3N,N0,N00}- bis(thiocyanato-jN)nickel(II)

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  Publication Details (including relevant citation   information):

  Acta Crystallographica Section E
  Structure Reports
  ISSN 1600-5368

  Nura Suleiman Gwaram, Nurul Azimah Ikmal Hisham,
  Hamid Khaledi* and Hapipah Mohd Ali
  Department of Chemistry, University of Malaya, 50603 Kuala   Lumpur, Malaysia
  Correspondence e-mail:
  Received 13 December 2010; accepted 15 December 2010


  In the title compound, [Ni(NCS)2(C13H19N3O)(H2O)], the NiII
  ion is six-coordinated by the N,N0,N00-tridentate Schiff   base,
  the N atoms of two thiocyanate ligands and one water O atom
  in a distorted octahedral geometry. Intramolecular C—H N
  and C—H O hydrogen bonds occur. In the crystal, O—
  H S, O—H O and C—H S hydrogen bonds link
  adjacent molecules into layers parallel to the ac plane.

  Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C)   = 0.003 A°
  R factor = 0.025; wR factor = 0.058; data-to-parameter ratio =   14.9.

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