Nura Suleiman Gwaram - Dichlorido{2-morpholino-N-[1-(2- pyridyl)ethylidene]ethanaminej 3N,N0,N00}zinc(II)

Version 1

      Publication Details (including relevant citation   information):

      Acta Cryst. (2011). E67, m55 [ doi:10.1107/S1600536810050671 ]

      Nurul Azimah Ikmal Hisham, Nura Suleiman Gwaram,
      Hamid Khaledi* and Hapipah Mohd Ali
      Department of Chemistry, University of Malaya, 50603 Kuala   Lumpur, Malaysia
      Correspondence e-mail:
      Received 30 November 2010; accepted 3 December 2010


      In the title compound, [ZnCl2(C13H19N3O)], the Schiff base
      ligand acts as an N,N0,N00-tridentate chelating agent, making
      two five-membered rings with the ZnII ion. The metal atom is
      five-coordinated by the Schiff base ligand and two Cl atoms   in
      a distorted square-pyramidal geometry. An intramolecular
      C—H Cl interaction occurs. In the crystal, adjacent molecules
      are linked together via C—H Cl hydrogen-bonding
      and long range C—H O and C—H Cl interactions into a
      three-dimensional network.

      Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C)   = 0.004 A°
      R factor = 0.034; wR factor = 0.091; data-to-parameter ratio =   16.4.

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