Nura Suleiman Gwaram - Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis({2-morpholino-N-[1-(2-pyridyl)e thylidene]ethanamine-[kappa]3N,N',N''}(thiocyanato-[kappa]N)cadmium)

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      Publication Details (including relevant citation   information):

     

        Acta Cryst. (2011). E67,     m251    [ doi:10.1107/S1600536811002480    ]  

      Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis({2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-[kappa]3N,N',N''}(thiocyanato-[kappa]N)cadmium)

      Cd-SCN X-ray pic.JPG

     

      Abstract:

      In the title complex,   [Cd2(NCS)4(C13H19N3O)2],   the two CdII ions are bridged by a pair of thiocyanate   N:S-bridging ligands around an inversion   center. One terminal thiocyanate N atom and one   N,N',N''-tridentate Schiff base ligand   complete a distorted CdN5S octahedral geometry about   each CdII atom. In the crystal, the Schiff base   aromatic rings of adjacent  molecules are arranged above   each other into infinite chains along the a axis with   alternate centroid-centroid separations of 3.5299 (13) and 3.7857   (13) Å.

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