Doris Melgarejo - A short, unsupported Cu(I)Cu(I) interaction, 2.65 .ANG., in a dinuclear guanidine chloride complex.

Document created by Doris Melgarejo on Aug 22, 2014
Version 1Show Document
  • View in full screen mode

  Publication Details (including relevant citation   information):

  Chemical Communications (Cambridge, United Kingdom)    (2010),  46(1),  136-138. Chiarella, Gina M.;   Melgarejo, Doris Y.; Rozanski, Alex; Hempte, Pierre; Perez, Lisa   M.; Reber, Christian; Fackler, John P., Jr.


  The reaction of CuCl with the neutral guanidine Hhpp ligand   (1,3,4,6,7,8-hexahydropyrimido[1,2-a]pyrimidine) yields two   cryst. polymorphs of the neutral dimer,   bis(1,3,4,6,7,8-hexahydropyrimido[1,2-a]pyrimidine)dichloro-di-copper(I),   which were characterized by x-ray crystallog. and 1H NMR and   Raman spectroscopy.  They have the shortest distance known   for a bridging unsupported copper(I)-copper(I) interaction.

  Address (URL): ar=2010&ManuscriptID=b918912b