Min Lu - (1) Chiral Brønsted Acid Catalyzed Enantioselective α-Aminoxylation of Enecarbamates

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  Publication Details (including relevant citation   information):

  Angew.   Chem. Int. Ed. 49, 8588   (2010). Hot paper, highlighted by itsFrontispiece. (highlighted   by Synfacts & Synform)




            A             practically simple, highly enantioselective             Brønsted acid catalyzed α-aminoxylation of             enecarbamates extends the substrate scope for the             α-aminoxylation to linear and aromatic ketones,             allowing convergent and stereoselective access to             valuable α-hydroxy ketones, β-amino alcohols, and                           cis-oxazolidinones.            


  Address (URL): http://onlinelibrary.wiley.com/doi/10.1002/anie.201002640/abstract