Naval Bajwa - Efficient and selective reduction protocols of the 2,2-dimethyl-1,3-benzodioxan-4-one functional group to readily provide both substituted salicylaldehydes and 2-hydroxybenzyl alcohols

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      Publication Details (including relevant citation   information):

                                 
           
         
           

              Author(s): Bajwa N,           Jennings MP        

           

             
              Source: JOURNAL OF ORGANIC           CHEMISTRY Volume: 71 Issue: 9 Pages: 3646-3649 Published: APR 28 2006       

           

              Times Cited: 10                 

         

      Abstract:

      Two complementary procedures have been developed that selectively   allow for the synthesis of either substituted salicylaldehydes or   the corresponding 2-hydroxylbenzyl alcohols upon treatment of the   2,2-dimethyl- 1,3-benzodioxan-4-one functional group with DIBAL-H   or LAH, respectively.

      Address (URL): http://pubs.acs.org/doi/full/10.1021/jo0601664