Halil Aktas - Nucleophilic Phosphinidene Complexes - Access and Applicability

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      Publication Details (including relevant citation   information):

      Syntheses, properties, and reactivities of nucleophilic   phosphinidene complexes [LnM=P-R] are reviewed.

      Abstract:

      Syntheses, properties, and reactivities of nucleophilic   phosphinidene complexes [LnM=P-R] are reviewed. Emphasis is   placed on the electronic tuning of this emerging class of   phosphorus reagents, using different ancillary ligands and   coordinatively unsaturated transitionmetal moieties. The   difference in applicability of the established stable 18-electron   and transient 16-electron phosphinidenes is addressed.

      Address (URL): http://onlinelibrary.wiley.com/doi/10.1002/anie.200905689/abstract