Halil Aktas - Nucleophilic Phosphinidene Complexes - Access and Applicability

Document created by Halil Aktas on Aug 22, 2014
Version 1Show Document
  • View in full screen mode

  Publication Details (including relevant citation   information):

  Syntheses, properties, and reactivities of nucleophilic   phosphinidene complexes [LnM=P-R] are reviewed.

  Abstract:

  Syntheses, properties, and reactivities of nucleophilic   phosphinidene complexes [LnM=P-R] are reviewed. Emphasis is   placed on the electronic tuning of this emerging class of   phosphorus reagents, using different ancillary ligands and   coordinatively unsaturated transitionmetal moieties. The   difference in applicability of the established stable 18-electron   and transient 16-electron phosphinidenes is addressed.

  Address (URL): http://onlinelibrary.wiley.com/doi/10.1002/anie.200905689/abstract

 

Attachments

    Outcomes