Ibrahim Eryazici - Square-Planar Pd(II), Pt(II), and Au(III) Terpyridine Complexes: Their Syntheses, Physical Properties, Supramolecular Constructs, and Biomedical Activities

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  Publication Details (including relevant citation   information):

  Eryazici, I.; Moorefield, C. N.; Newkome, G.   R., Chemical Reviews,  2008, 108(6), 1834-1895.

  Abstract:

 

Table of Contents

     
  • 1. Introduction  
  •  
  • 2. Chemistry and Properties    
           
    •       2.1. Syntheses      
    •      
    • 2.2. Characterization      
    •      
    • 2.3. Single X-ray Crystal Structures and Their Molecular       Packing      
    •      
    • 2.4. Dimerization and Its Constant (KD)      
    •      
    • 2.5. Photophysical Properties      
    •      
    • 2.6. Electrochemical Properties      
    •      
    • 2.7. Fluxionality      
    •    
     
  •  
  • 3. Applications of Mononuclear Terpyridine Complexes    
           
    •       3.1. Luminescent Pt−Terpyridine Complexes      
    •      
    • 3.2. Molecular Stacking and Induced Self-Assembly      
    •      
    • 3.3. Molecular Sensors and Switches      
    •      
    • 3.4. Photocatalytic Activities      
    •      
    • 3.5. Miscellaneous Applications      
    •    
     
  •  
  • 4. Metallo-Supramolecular Terpyridine Architectures    
           
    •       4.1. Dyads and Triads      
    •      
    • 4.2. Supramolecular Self-Assemblies      
    •      
    • 4.3. Molecular Recognition by Host−Guest Interaction      
    •      
    • 4.4. Multimetallic Peptide Scaffolds      
    •    
     
  •  
  • 5. Biological Activities    
           
    •       5.1. DNA Intercalation        
                 
      •           5.1.1. UV−Vis Spectroscopic Analysis and Binding Modes          
      •          
      • 5.1.2. Viscosity and Thermal Denaturation          
      •          
      • 5.1.3. Induced Circular Dichroism          
      •          
      • 5.1.4. Competitive Fluorescence Spectroscopy          
      •          
      • 5.1.5. Closed Circular DNA          
      •          
      • 5.1.6. Stereochemical Changes in DNA          
      •          
      • 5.1.7. Site-Specific Intercalation          
      •          
      • 5.1.8. Other Mononuclear Intercalators          
      •          
      • 5.1.9. Multinuclear Intercalators          
      •        
           
    •      
    • 5.2. Covalent Binding to Biomolecules      
    •      
    • 5.3. Labeling Biomolecules      
    •      
    • 5.4. Cytotoxicity        
                 
      •           5.4.1. Chemotherapeutic Agents          
      •          
      • 5.4.2. Radiotherapeutic Agents          
      •        
           
    •    
     
  •  
  • 6. Conclusion  

  Address (URL): http://pubs.acs.org/doi/abs/10.1021/cr0781059

 

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