Ibrahim Eryazici - Imine-Linked Microporous Polymer Organic Frameworks

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  Publication Details (including relevant citation   information):

  Pandey, P.,Katsoulidis,   A. P., Eryazici, I., Wu, Y., Kanatzidis, M. G.,   Nguyen, S. T., Chemistry of Materials,   2010,22(17), 4974-4979.


  Imine-linked microporous polymer organic frameworks (POFs) were   synthesized via Schiff base condensation between   1,3,5-triformylbenzene and several readily available diamine   monomers. Our facile, one-pot approach results in quantitative   yields of POFs with the flexibility to incorporate several   functional groups in their pores for tuning the interaction of   their surface with different guest molecules. Synthesized POFs   exhibit high specific surface areas (up to 1500 m2 g−1) as well as   high isosteric heats of H2  adsorption (up to 8.2 kJ mol−1).

  Address (URL): http://pubs.acs.org/doi/abs/10.1021/cm101157w