Tathagata Mukherjee - CuO Nanoparticles Catalyzed C−N, C−O, and C−S Cross-Coupling Reactions: Scope and Mechanism

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  Publication Details (including relevant citation   information):

  J. Org. Chem.,  2009, 74 (5), pp 1971–1976

  Publication Date (Web): January 27, 2009   (Article)

  DOI: 10.1021/jo8024253


  CuO nanoparticles have been studied for C-N, C-O, and C-S bond   formations via cross-coupling

  reactions of nitrogen, oxygen, and sulfur nucleophiles with aryl   halides. Amides, amines, imidazoles,

  phenols, alcohols and thiols undergo reactions with aryl iodides   in the presence of a base such as KOH, Cs2CO3, and K2CO3 at   moderate temperature. The procedure is simple, general,   ligand-free, and efficient to afford the cross-coupled products   in high yield.

  Address (URL): http://pubs.acs.org/doi/pdf/10.1021/jo8024253