Lei Gao - Azadipyrromethene-Based Conjugated Oligomers with Near-IR Absorption and High Electron Affinity

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  Publication Details (including relevant citation   information):

  Organic Letters, 2011 ASAP

  DOI: 10.1021/ol202211t


  Solution-processable conjugated oligomers incorporating red-light   absorbing azadipyrromethenes (aza-DIPY) within the main chain   were synthesized via palladium-catalyzed Sonogashira coupling   reactions. Thin films of these compounds absorbed light up   to1000   nm and displayed reversible reductions as ascertained by cyclic   voltammetry experiments. Reactions with trifluoroboron etherate   yielded materials displaying a unique combination of good   solubility in organic solvents, low optical band gaps   (1.3   eV), and high electron affinity (4.5   eV).

  Address (URL): http://pubs.acs.org/doi/abs/10.1021/ol202211t?prevSearch=%255Bauthor%253A%2BLei% 2BGao%255D%2BNOT%2B%255Batype%253A%2Bad%255D%2BNOT%2B%255Batype%253A%2Bacs-toc% 2 55D&searchHistoryKey=