Martin Lang - Stephanosporin, a 'Traceless' Precursor of 2-Chloro-4-nitrophenol in the Gasteromycete Stephanospora caroticolor

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  Publication Details (including relevant citation   information):

  Martin Lang, Peter Spiteller, Veronika Hellwig, Wolfgang Steglich

  Angew. Chem. Int. Ed. 2001,   40, 1704-5

  Angew. Chem. 2001, 113,   1749-51


  The fruiting bodies of the carrot truffle Stephanospora   caroticolor were extracted yielding two pigments,   2-chloro-4-nitrophenol and stephanosporin. The structure of   stephanosporin was confirmed by synthesis followed by analysis by   GC/MS.  Also isolated were 4-hydroxyacetanilide,   4-amino-2-chlorophenol and 4-nitrophenol. A scheme for the   enzymic degradation of stephanosporin to 2-chloro-4-nitrophenol   is presented.

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