Alexander Shaplov - Radical (co)polymerization of acrylonitrile in ionic liquids

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      Publication Details (including relevant citation   information):

      Ya.S. Vygodskii, O.A. Melnik, E.I. Lozinskaya, A.S. Shaplov.   Vysokomol. Soed. (Polymer Science Ser.   B), Ser. B, 2005, v. 47, no. 4, P.   122-126 (Chem Abstr 2005, 143, 173431).


      The free-radical polymerization of acrylonitrile and its   copolymerization with methyl methacrylate in ionic liquids based   on 1,3-dialkyl-substituted imidazole were studied. It was shown   that, in contrast to the case of common molecular solvents, the   polymerization and copolymerization in liquid organic salts give   highmolecular-mass polyacrylonitrile and copolymers with high   yields, with the former polymer showing a higher onset   temperature of degradation.

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