Mohammad Halvagar - A heterocyclic organogallium peroxide with two dialkylgallium groups bridged by a peroxide dianion

Version 1

      Publication Details (including relevant citation   information):

      Chem. Commun., 2009, 4269-4271

     

      Abstract:

     

     

        Treatment of     Li[H2GaR2]     1 [R =     CH(SiMe3)2]     with the hydrogen peroxide adduct     (H2O2)2·DABCO     (DABCO = diazabicyclooctane) afforded a heterocyclic digallium     peroxide,     [R2Ga(μ,η11-O2)(μ-OH)GaR2]Li(DABCO)     (2), in which two dialkylgallium groups are bridged by an     oxidizing peroxo and a hydroxo ligand.  


     
     
        Graphical abstract: A heterocyclic organogallium peroxide with two dialkylgallium groups bridged by a peroxide dianion 

      Address (URL): http://pubs.rsc.org/en/Content/ArticleLanding/2009/CC/b906392g