Mohammad Halvagar - A heterocyclic organogallium peroxide with two dialkylgallium groups bridged by a peroxide dianion

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  Publication Details (including relevant citation   information):

  Chem. Commun., 2009, 4269-4271

 

  Abstract:

 

 

    Treatment of     Li[H2GaR2]     1 [R =     CH(SiMe3)2]     with the hydrogen peroxide adduct     (H2O2)2·DABCO     (DABCO = diazabicyclooctane) afforded a heterocyclic digallium     peroxide,     [R2Ga(μ,η11-O2)(μ-OH)GaR2]Li(DABCO)     (2), in which two dialkylgallium groups are bridged by an     oxidizing peroxo and a hydroxo ligand.  


 
 
    Graphical abstract: A heterocyclic organogallium peroxide with two dialkylgallium groups bridged by a peroxide dianion 

  Address (URL): http://pubs.rsc.org/en/Content/ArticleLanding/2009/CC/b906392g

 

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