Mohammad Halvagar - Strongly Oxidizing and Reducing Functions Combined in a Single Compound: An Alkyl Gallium Peroxide Possessing a Nine-Membered (GaR)3(O2)3 Heterocycle†

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      Publication Details (including relevant citation   information):

     

      Angewandte Chemie International Edition

      Volume 47, Issue 10, pages   1955–1957, February 22, 2008

      Abstract:

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      Organoelement peroxides of the heavier Group 13   elements form a class of extraordinarily reactive compounds,   which decompose spontaneously by intramolecular redox processes   as a result of the close contact of oxidizing peroxo groups and   reducing E[BOND]C   bonds. The synthesis of a unique compound is presented, in which   three peroxo ligands bridge three alkyl gallium groups by the   formation of a nine-membered heterocycle (see structural   formula).

      Address (URL): http://onlinelibrary.wiley.com/doi/10.1002/anie.200704739/abstract