Veronika Zinovyeva - Electrosynthesis as a Powerful Method for Generation of Catalytic Intermediates: Straightforward Isolation of a Palladium Aryl Halide Oxidative Addition Product

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      Publication Details (including relevant citation   information):

      Chemistry   A European Journal 2011,   17, 9901-9906.

      Zinovyeva   V. A., Luo   C., Fournier S., Devillers C. H., Cattey H., Doucet H., Hierso   J.-C., Lucas D.

      Abstract:

      Polyphosphane ligands of controlled conformation   promote highly efficient palladium-catalyzed cross-coupling   reactions. Electrosynthesis has been used as a new   straightforward method to obtain important intermediates in the   search for a better mechanistic understanding. As a proof of   concept, the facile synthesis of a phenyl iodopalladium(II)   complex (2) was conducted at the electrolysis   scale from a readily electrogenerated unstable Pd0  precursor (see scheme).

     

      Address (URL): http://onlinelibrary.wiley.com/doi/10.1002/chem.201100629/abstract;jsessionid=F8 CA9F8055B37E566506D94765845B99.d03t02