Diane Dickie - A Unique Three-Dimensional Coordination Cluster Based on a Silver Carbene Complex.

Document created by Diane Dickie on Aug 22, 2014
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  Publication Details (including relevant citation   information): Mrutu,Agnes, Dickie,Diane A.,   Goldberg,Karen I., Kemp,Richard A., Inorg. Chem. (Washington,   DC, U. S.), 2011, 50 (7), pp   2729-2731

  Abstract: In an attempt to perform a simple   anion-exchange reaction on a pincer-carbene-ligated Ni complex   using AgNO3, the authors instead obtained an unexpected   three-dimensional (3D) Ag7 cluster contg. a [Ag6] core in a   twisted-bowtie geometry. The reverse-transmetalation reaction by   which the carbene is transferred from Ni to Ag is virtually   unprecedented. The CNC pincer-carbene ligands exhibit unusual   bridging modes of ligand bonding for all three donor atoms.   Another unique feature is that the final structure exhibits a   3-dimensional structure brought about by the connection of   two-dimensional layers of the [Ag6] core via a seventh Ag ion.   [on SciFinder(R)]

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