Ralf Haiges - Energetic Bis(3,5-dinitro-1H-1,2,4-triazolyl)dihydro- and dichloroborates and Bis(5-nitro-2H-tetrazolyl)-, Bis(5-(trinitromethyl)-2H-tetrazolyl)-, and Bis(5-(fluorodinitromethyl)-2H-tetrazolyl)dihydroborate.

Document created by Ralf Haiges on Aug 22, 2014
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  Publication Details (including relevant citation   information): Haiges, Ralf, Jones, C. Bigler, Christe,   Karl O., Inorg. Chem., 2013,   52 (9), pp 5551-5558

  Abstract: Salts of   bis(3,5-dinitro-1H-1,2,4-triazolyl)dihydro- and dichloroborate   and bis(5-nitro-2H-tetrazolyl)-,   bis(5-trinitromethyl-2H-tetrazolyl)-, and   bis(5-fluorodinitromethyl-2H-tetrazolyl)dihydroborate anions have   been synthesized by the treatment of hydroborates or   chloroborates with the corresponding nitroazoles or   nitroazolates, resp. Alkali-metal salts of these dihydroborates   are energetic and can be shock-sensitive, while salts with larger   org. cations, such as NMe4+, PPh4+, or (Ph3P)2N+, are less   sensitive. Poly(nitroazolyl)borates are promising candidates for   a new class of environmentally benign energetic materials and   high-oxygen carriers. [on SciFinder(R)]

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