Jeremiah Hubbard - Synthesis of 2-alkyl-substituted benzimidazoles by thermal decomposition of 2-azibenzenamines in the presence of an aldehyde

Document created by Jeremiah Hubbard on Aug 22, 2014
Version 1Show Document
  • View in full screen mode

  Publication Details (including relevant citation   information):

  Synthesis   of 2-alkyl-substituted benzimidazoles by thermal decomposition of   2-azibenzenamines in

  the presence   of an aldehyde. Wallace, Jeffery M.; Söderberg, Björn C. G.;   Hubbard, Jeremiah W. Synthetic   Communications 2006, 36,   3425-3439

  Abstract:

  2‐Substituted benzimidazoles were prepared by reaction of   2‐azidoaminobenzenes with aldehydes under thermal conditions. The   reaction probably proceeds via a sequential imine formation,   azide decomposition forming a nitrene, and electrocyclization.

  Address (URL): http://dx.doi.org/10.1080/00397910600941497

 

Attachments

    Outcomes