Jeremiah Hubbard - Palladium-catalyzed N-heteroannulations of N-allyl- or N-benzyl-2-nitrobenzenamines: Synthesis of 2-substituted benzimidazoles

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  Palladium-catalyzed   N-heteroannulations of N-allyl- or   N-benzyl-2-nitrobenzenamines:

  Synthesis of   2-substituted benzimidazoles. Hubbard, Jeremiah W.; Piegols,   Adam M.; Söderberg,   Björn C. G. Tetrahedron 2007,   63(30), 7077-7085


  A palladium-catalyzed reductive N-heteroannulation of   N-allyl- or N-benzyl-2-nitrobenzenamines, using   carbon monoxide as the ultimate reducing agent, affording   2-substituted benzimidazoles has been developed.

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