Ralf Haiges - The Syntheses and Structure of the Vanadium(IV) and Vanadium(V) Binary Azides V(N3)4, [V(N3)6]2-, and [V(N3)6]-.

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      Publication Details (including relevant citation   information): Haiges, Ralf, Boatz, Jerry A., Christe,   Karl O., Angew. Chem., Int. Ed., 2010,   49 (43), pp 8008-8012, S8008/1-S8008/51

      Abstract: The vanadium(IV) and vanadium(V)   binary azides V(N3)4, [PPh4]2[V(N3)6], [PNP]2[V(N3)6] and   [NMe4][V(N3)6] were prepd. and characterized by IR and Raman   spectroscopy. V(N3)4 and [NMe4][V(N3)6] are very shock-sensitive   and can explode violently upon the slightest provocation, while   the vanadium(IV) anionic complexes are more stable. The   structures of [PPh4]2[V(N3)6] and [PNP]2[V(N3)6] were studied by   x-ray crystallog. and theor. calcns. [on SciFinder(R)]

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