Saleesh Kumar Nambalan Sivaraman - Highly Chromic, Proton-Responsive Phenyl Pyrimidones

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  Publication Details (including relevant citation   information):

 

 
    Authors    

      Jyothi Dhuguru, Chirag Gheewala, NS Saleesh Kumar, James N       Wilson    

 
 

 

 
    Publication date    

      2011/7/26    

 
 

 

 
    Journal name    

      Organic letters    

 
 

 

 
    Volume    

      13    

 
 

 

 
    Issue    

      16    

 
 

 

 
    Pages    

      4188-4191    

 
 

 

 
    Publisher    

      American Chemical Society    

 
 

 

 
    Description    

      Aryl pyrimidones are pharmacologically relevant compounds       whose optical properties have
      only been partially explored. We report the synthesis and       optical characterization of a series
      of aryl-and diaryl-2 (1 H)-pyrimidones. The electronic       transitions of these chromophores are
      modulated by the extent of conjugation between the pendant       phenyl ring and the pyrimidone
      core as well as the presence of electron-donating       auxochromes. Monoprotonation of the
      pyrimidone ring results in large hyperchromic and       bathochromic shifts as well as switching ...   

 

 

 
   
      Total citations      

        Cited by 9     

   
 

  Abstract:

  Address (URL): http://http://pubs.acs.org/doi/abs/10.1021/ol2014945

 

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