Saleesh Kumar Nambalan Sivaraman - Luminescent Charge-Transfer Complexes: Tuning Emission in Binary Fluorophore Mixtures

Version 1

      Publication Details (including relevant citation   information):

     

     
        Authors    

          Maneesh D Gujrati, NS Saleesh Kumar, Adrienne S Brown, Burjor       Captain, James N Wilson    

     
     

     

     
        Publication date    

          2011/5/6    

     
     

     

     
        Journal name    

          Langmuir    

     
     

     

     
        Volume    

          27    

     
     

     

     
        Issue    

          11    

     
     

     

     
        Pages    

          6554-6558    

     
     

     

     
        Publisher    

          American Chemical Society    

     
     

     

     
        Description    

          Charge-transfer (CT) complexes composed of a π-electron-poor       naphthalene diimide (NDI)
          derivative combined with a series of π-electron-rich donors       were investigated. Solutions of
          the CT complexes are nonemissive; however, solid-state       complexes and aqueous
          suspensions display emission that is dependent on the energy       of the **** of the electron
          donor. Crystallographic analysis of a pyrene–NDI complex       reveals columnar packing and a
          high degree of frontier molecular orbital (FMO) overlap that       likely contributes to the ...   

     

     

     
       
          Total citations      

            Cited by 9     

       
     

      Abstract:

      Address (URL): http://pubs.acs.org/doi/abs/10.1021/la2012809