Anat Milo - An achiral manganese salen catalyst encapsulated in a peptidic phosphonate homochiral solid for the enantioselective formation of diols by consecutive epoxidation and hydration reactions.

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      Publication Details (including relevant citation   information):

      Milo, Anat, Neumann, Ronny 2011 47 (9)   2535-2537

      Abstract: An insoluble, porous, amorphous,   homochiral material based on a polypeptide titanium-phosphonate   scaffold with an encapsulated achiral Mn(III)-salen was prepared   and characterized. Consecutive epoxidation and hydration of   styrene and its derivatives by aqueous hypochlorite in THF showed   the highly enantioselective (>99%) formation of styrene diol   derivatives.

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