Diane Dickie - Synthesis and lanthanide coordination chemistry of CMPO-decorated dibenzothiophene and dibenzothiophene sulfone platforms.

Version 1

      Publication Details (including relevant citation   information):

      Rosario-Amorin, Daniel, Ouizem, Sabrina, Dickie, Diane A., Hay,   Benjamin P., Podair, Julien, Delmau, Laetitia H., Paine, Robert   T. Polyhedron 102 103-110

      Abstract: Syntheses and spectroscopic   characterization data for two new hybrid chelating ligands,   4,6-bis[(diphenyl-N,N-diethylcarbamoylmethylphosphine   oxide)methyl]dibenzothiophene (2) and   4,6-bis[(diphenyl-N,N-diethylcarbamoylmethylphosphine   oxide)methyl]dibenzothiophene 5,5-dioxide (3), that contain two   CMPO (carbamoylmethylphosphine oxide) fragments grafted onto   dibenzothiophene and dibenzothiophene sulfone platforms, resp.,   are presented. Coordination chem. with selected lanthanide   nitrates is described along with a x-ray crystal structure detn.   for an unexpected Eu(III) complex, Eu(4)(NO3)3 that contains the   intermediate ligand oxidn. species   4,6-bis[(diphenyl-N,N-diethylcarbamoylmethylphosphine   oxide)methyl]dibenzothiophene 5-oxide (4). [on SciFinder(R)]

      Address (URL):