Diane Dickie - [2,6-Bis(di-tert-butylphosphinomethyl)phenyl-κ3P,C1,P'](nitrato-κO)nickel(II).

Version 1

      Publication Details (including relevant citation   information):

      Boro, Brian J., Dickie, Diane A., Duesler, Eileen N., Goldberg,   Karen I., Kemp, Richard A. Acta Crystallographica, Section E:   Structure Reports Online 64 (11) m1402,   m1402/1-m1402/8-

      Abstract: The Ni(II) atom in the title compd.,   [Ni(C24H43P2)(NO3)] adopts a distorted square planar geometry   with the P atoms in a trans arrangement. The compd. contains a   2-fold rotational axis with the nitrate group offset from this   axis, except for an O atom of the nitrate group, generating 2   positions of 50% occupancy for the other atoms of the nitrate   group. Crystal data: orthorhombic, space group Fdd2, a =   24.0023(14), b = 12.6350(6), c = 17.6528(6) Å, Z = 8, R = 0.030,   Rw = 0.099 for 3703 obsd. reflections with I > 2σ(I) and 156   refined parameters at T = 225(2) K. The at. coordinates and   bonding distances are given. [on SciFinder(R)]

      Address (URL): http://journals.iucr.org/e/issues/2008/11/00/at2643/at2643.pdf