Publication Details (including relevant citation information):
Lopez-Torres, E, Calatayud, D G, Mendiola, M A, Pastor, C J, Procopio, J R Zeitschrift fur Anorganische und Allgemeine Chemie 2006 632 (15) 2471-2474
Abstract: The first complex with benzilbis(thiosemicarbazone) LH6 acting only as a bridge between two metallic centres through the sulfur atoms, was obtained from the reaction with methylmercury chloride. This complex shows a 1:2 ligand : mercury ratio and has been spectroscopically characterized and recrystallized in toluene. The ligand acts as a dianion, with an intermediate situation between cis and trans dispositions, and it is bonded to both methylmercury moieties through the sulfur atoms, giving a binuclear complex with linear CS coordination for the mercury atoms.
Address (URL): ISI:000242259000018