Andrew Behrle - Insertion of tBuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry

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      Publication Details (including relevant citation   information):

      Andrew C. Behrle  and Justin R.   Walensky *
      Department of Chemistry, University of   Missouri, Columbia, MO 65211, USA. E-mail: walenskyj@missouri.edu

       

      DOI: 10.1039/C6DT00776G (Paper) Dalton   Trans., 2016, 45, 10042-10049

      Abstract:

      The reactivity of thorium–phosphido and   thorium–arsenido bonds was probed using tert-butyl isocyanide, tBuNC. Reaction of   (C5Me5)2Th[E(H)R]2,   E = P, As; R =   2,4,6-iPr3C6H2,   2,4,6-Me3C6H2  with tBuNC   affords the first phosphaazaallene and arsaazaallene moieties   with an f-element.

      Address (URL): http://pubs.rsc.org/en/content/articlehtml/2016/DT/C6DT00776G