Frank Schuhmacher - A traceless photocleavable linker for the automated glycan assembly of carbohydrates with free reducing ends

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      Publication Details (including relevant citation   information):

      Wilsdorf, M., Schmidt, D., Bartetzko, M. P., Dallabernardina, P.,   Schuhmacher, F., Seeberger, P. H., Pfrengle, F. Chemical   Communications 2016 52 (66)   10187-10189

      Abstract: We report a traceless photocleavable   linker for the automated glycan assembly of carbohydrates with   free reducing ends. The reductive-labile functionality in the   linker tolerates all commonly used reagents and protocols for   automated glycan assembly, as demonstrated with the successful   preparation of nine plant cell wall-related oligosaccharides, and   is cleaved by hydrogenolysis.

      Address (URL): http://dx.doi.org/10.1039/C6CC04954K