Jean-Claude Bunzli - Aquachlorobis(4,4 ',4 ''-tri-tert-butyl-2,2 ';6 ',2 ''-terpyridine-kappa N-3)terbium(III) diperchlorate ethanol disolvate

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  Publication Details (including relevant citation   information):

  Murner,H.R., Scopelliti,R., Bunzli,J.C.G. Acta   Crystallographica Section C-Crystal Structure Communications  2002 58 m434-m435

  Abstract: In the title compound,   [TbCl(C27H35N3)(2) (H2O)](ClO4)(2).-2C(2)H(6)O, the Tb-III ion   has a coordination number of eight, composed of two tridentate   substituted-terpyridine ligands, a water molecule and a bound Cl-   anion. The first coordination shell can be described as a   distorted bicapped trigonal prism. The dihedral angles between   pyridine rings belonging to the same tpy ligand range from 5.2   (5) to 16.8 (5)degrees

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