Jean-Claude Bunzli - A new versatile methodology for the synthesis of 4-halogenated-6-diethylcarbamoylpyridine-2-carboxylic acids

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  Publication Details (including relevant citation   information):

  Chauvin,A.S., Tripier,R., Bunzli,J.C.G. Tetrahedron   Letters 2001 42 (17) 3089-3091

  Abstract: Convenient syntheses of dipicolinic or   chelidamic acid derivatives including   4-X-6-diethylcarbamoyl-pyridine-2-carboxylic acid (X = H, Cl, Br)   and 4-chloro-6-(3-oxo-3-phenylpropionyl)pyridine-2-carboxylic   acid methyl ester are described. These compounds are important   synthons for the synthesis of non-symmetric tridentate aromatic   chelating agents as well as for the design of ditopic ligands   targeted for the elaboration of functional dimetallic helicates.   (C) 2001 Elsevier Science Ltd. All rights reserved

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